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$2.00 Integrated Rate Law (2 questions) 1st order vs 2nd order

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omega7001
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When do you use integrated rate equation (1st order) and when do you use integrated rate equation (2nd order)?

Question 1. N2O5 (g)-->N2O4 (g) + 1/2O2 (g). If 2.50moles of N2O5 (g) are placed in a 5.00L container, how many moles of N2O5 would remain after 1.00minute? K=1.68x10^-2s^-1. Question 2. 2NOBr (g)-->2NO (g) + Br2 (g). K=0.810L/mol*sec. If there is an initial concentration of NOBr=4.00x10^-3M, how many seconds does it take to use up 1.50x10^-3M NOBr?

 

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  • Posted on Jul 03, 2011 at 12:45:45PM
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  • Posted on Jul 03, 2011 at 12:46:56PM
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Preview: ... (g) according to integrated rate equation (2nd order) k=0.810l/mol*sec 1/1.50x10^-3 ...

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Preview: ... when the ln[A] vs time for a reaction shows a linear graph. Use the 2 nd order integrated rate equation when 1/[A] vs time shows a linear graph. Basically, you are looking for a direct relationship with a linear graph, and integrated rate equations are based on direct relationships.   The reaction in Question 1 is 1 st order. For N2O5 (g)-->N2O4 (g) + 1/2O2 (g) The ...

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